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Quenching temperature and cooling method of Die Tool Steel (STD) of the following is?
① quenching temperature: 750 ~ 800 ℃, cooling method: cooling the air
② tempering temperature: 850 ~ 900 ℃, cooling methods: air cooling to
③ quenching temperature: 650 ~ 700 ℃, cooling methods: air cooling of
④ quenching temperature: 1000 ~ 1050 ℃, cooling methods: air cooling
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